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Effect of the type of ion-pairing reagent in reversed-phase ion-pair chromatography (1985)

Bartha, Á. ; Vigh, Gy. ; Billiet, H. ; [et al.]

Springer

Chromatographia 20 (1985), S. 587-590

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ISSN: 1612-1112

Keywords: Column liquid chromatography ; Ion-pair chromatography ; Sulfonate pairing ion ; Adsorption isotherms

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary The retention of positively and negatively charged and neutral solutes was studied in an aqueous phosphate buffer eluent, with constant inorganic-counterion concentration, on ODS-Hypersil stationary phase in the presence of various sulfonic acid ion-pairing reagents. The adsorption isotherms of the ion-pairing reagents d-camphor-10-sulfonic acid, sodium cyclohexylsulfamic acid and sodium alkylsulfonates (butyl-, hexyl- and octyl-) were determined by the breakthrough method.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02263216

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