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Digitale Medien

Limitations of the assumption of negligible film thickness in capillary chromatography (1990)

Schisla, D. ; Carr, P. W.

Springer

Chromatographia 29 (1990), S. 606-608

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Details

ISSN: 1612-1112

Schlagwort(e): Capillary gas chromatography ; Thick-film

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Summary The validity of Golay's assumption of a thin film in his theoretical development of capillary chromatography is evaluated by comparing it to Ari's theory which takes into account film curvature. The two solutions are compared using previously published capillary gas chromatography data. The results show that deviations between the theories are insignificant at conventional aspect ratios of 3 %, but can be important at 10 %.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF02261232

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