ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, trans-[Pd(C6H5)(C8H7O2S)(C18H15P)2], crystallizes in two modifications differing only in the orientation of the 2-methylthiobenzoato ligand. In both cases, this ligand binds to the metal centre via one O atom in a monodentate fashion. The only significant difference is a rotation about the C(Ph)—COO bond, with O—C—C—C torsion angles having values of 6.3 (7) and 157.3 (3)° in the two isomeric forms.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270199015449