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N-Ethylazatribenzo-21-crown-7 (2000)

Bryan, Jeffrey C. ; Lavis, Jerôme M. ; Hay, Benjamin P. ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 56 (2000), S. 391-392

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The structure of the title compound, 25-ethyl-2,5,12,15,22,28-hexaoxa-25-azatetracyclo[27.4.0.06,11.016,21]tritriaconta-1(29),6(11),7,9,16(21),17,19,30,32-nonaene, C28H33NO6, does not exhibit a binding cavity for cations, but is collapsed in on itself. The conformation is unique among known tribenzo-21-crown-7 structures, and may be a result of intermolecular (C—H...π) and intramolecular (C—H...O) hydrogen bonding.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270199016534

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