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trans-Bis(ethanolamine-N,O)bis(saccharinato-N)copper(II) (2001)

Yilmaz, Veysel T. ; Andac, Omer ; Topcu, Yildiray ; [et al.]

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. 271-272

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: In the title complex, [Cu(C7H4NO3S)2(C2H7NO)2], the CuII centre lies on an inversion centre and exhibits octahedral coordination, with the two ethanolamine (Hea) and two saccharinate [sac; anionic 1,2-benzisothiazol-3(2H)-one 1,1-dioxide] ligands in a trans configuration. The bidentate Hea ligands bridge axial and equatorial positions and the sac anions occupy equatorial sites around the distorted octahedral copper(II) centre [Cu—O = 2.3263 (16), Cu—NHea = 1.9923 (16) and Cu—Nsac = 2.1776 (16) Å].

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270100019867

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