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Bis(triethanolamine-N,O,O′)nickel(II) bis(saccharinate) (2001)

Topcu, Yildiray ; Andac, Omer ; Yilmaz, Veysel T. ; [et al.]

Copenhagen : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. m82-m84

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ISSN: 1600-5368

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The structure of the title compound, [Ni(C6H15NO3)2](C7H4NO3S)2, consists of a cationic [Ni(TEA)2]2+ and two anionic (SAC)− moieties (TEA is triethanolamine and SAC is the saccharinate anion). Two TEA ligands coordinate to the NiII ion through four O atoms and two N atoms acting as tridentate ligands (N,O,O′) in a distorted octahedral environment, with the bond distances [d(Ni—O) = 2.078 (2) and 2.082 (2) Å, and d(Ni—N) = 2.108 (2) Å]. SAC anions participate in intermolecular hydrogen bonding with the hydroxyl H atoms of the TEA ligands to form a three-dimensional network.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S1600536801001878

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