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  • 1
    Electronic Resource
    Electronic Resource
    cis-(1,4-Dithiane-S,S′)diiodoplatinum(II) (2001)
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 57 (2001), S. m114-m116 
    Details
    ISSN: 1600-5368
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The title compound, [PtI2(S2C4H8)], consists of a 1,4-dithiane and two iodo ligands coordinated to a Pt atom in a distorted square-planar cis-system with Pt on a twofold axis. The dithiane forms a bidentate chelate with Pt, bonding via the S atoms. The Pt—I bonds are 2.6035 (5) Å and the Pt—S bonds 2.2751 (16) Å. The Pt—S bond is influenced mainly by the cis-chelate effect and the Pt—I bond by the trans-influence of sulfur.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S1600536801002951
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