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Anomaly in Cp/Cv: A possible signature of a liquid-glass transition (1991)

Grimsditch, M. ; Rivier, N.

Woodbury, NY : American Institute of Physics (AIP)

Applied Physics Letters 58 (1991), S. 2345-2347

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ISSN: 1077-3118

Source: AIP Digital Archive

Topics: Physics

Notes: Brillouin scattering from two classic glass-forming materials, ZnCl2 and glycerol, reveals a maximum in the ratio (γ) of specific heats Cp and Cv as a function of temperature. We propose that the temperature at which the maximum in γ occurs in our materials may be indicative of a "liquid-like'' to "solid-like'' transformation. As such it may be a convenient thermodynamic signature of a ‘glass' transition.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.104920

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