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Electronic structure of Sb substituted in BaBiO3 (1991)

Eibschütz, M. ; Cava, R. J. ; Krajewski, J. J. ; [et al.]

Woodbury, NY : American Institute of Physics (AIP)

Applied Physics Letters 58 (1991), S. 1914-1916

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ISSN: 1077-3118

Source: AIP Digital Archive

Topics: Physics

Notes: The Mössbauer effect of the 37.2 keV γ transition of 121Sb has been employed to study the electronic configuration of Sb ions in BaBi1−xSbxO3 with x=0.2, 0.4, and 0.5. A single resonance absorption line is observed. The isomer shift changes slightly with Sb content and falls in the region corresponding to an Sb(V) valence state. The isomer shift of 7.6 mm/s is significantly depressed (∼1 mm/s) relative to its value in a typical Sb(V)O6 chromophore and indicates a high degree of covalency, corresponding to significant 5sm5pn hybridization.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.105072

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