ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
A charge transfer (CT) excited state has been identified in the photoelectron spectrum of Cl−NH3. A narrow band at 4.0 eV binding energy (BE) is assigned to ionization of Cl−, and a broad band peaking at 6.45±0.15 eV BE corresponds to a CT state, Cl−NH+3. The assignments are confirmed by ab initio calculations, yielding binding energies of 3.88 and 6.36 eV.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.465913