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High pressure transformations of NaOH (1993)

Beck, Horst P. ; Lederer, Gunda

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 98 (1993), S. 7289-7294

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The structures of two high pressure modifications of NaOH have been determined by in situ x-ray measurements with a diamond anvil cell. Thermodynamic data for the transformation are derived from the P,T diagram. The structures are discussed and especially the influence of the H atoms on characteristic deformations. The compressibility of α-NaOH shows an anomaly, which can be explained by a continuous transformation to yet another new modification, which is isotypic with the low-temperature form of NaOD.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.464721

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