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Digitale Medien

Growth of titanium nitride: From clusters to microcrystals (1993)

Chen, Z. Y. ; Castleman, A. W.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 98 (1993), S. 231-235

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Details

ISSN: 1089-7690

Quelle: AIP Digital Archive

Thema: Physik , Chemie und Pharmazie

Notizen: Time-of-flight mass spectrometry is used to investigate (TiN)n+ clusters produced by a laser-induced plasma reactor source. The mass spectral abundance patterns indicate that the clusters have cubic structures resembling subunits of the fcc lattice of solid TiN. The primary stoichiometries observed are (TiN)n+ (n=1–126), except for TinNn−1+ (n=14, 63). The most stable structures of the clusters are cuboids, in some cases containing a completed terrace. Even at the very early stages of crystal growth, the gas-phase clusters prefer a cubic crystalline atomic arrangement with a highly symmetric structure.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1063/1.464669

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