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Stimulated soft electron spin echo envelope modulation spectroscopy (1992)

Hustedt, E. J. ; Schweiger, A. ; Ernst, R. R.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 96 (1992), S. 4954-4962

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: An improved technique of electron spin echo envelope modulation (ESEEM) spectroscopy using soft pulses is proposed. It is functionally related to the standard three-pulse stimulated echo experiment, but has an improved bandwidth. The general class of soft-ESEEM experiments is analyzed theoretically by using a product operator formalism. The predicted features are verified experimentally, in particular, the lack of blind spots and the observation of high modulation frequencies.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.462738

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