Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
96 (1992), S. 4509-4517
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The Fulton–Gouterman transformation is applied to the dynamical E–e Jahn–Teller problem. This approach leads to an unconventional way of visualizing the exact eigensolutions of the problem. It turns out that in the upper energy region, eigenfunctions with unexpected behavior make their appearance ("exotic states''). They practically have no distortion in the oscillatory subspace, whereas eigenfunctions of large radial oscillatory displacement are found in their immediate energetic neighborhood. In a rough way, these exotic states may be attached to the upper potential sheet of the "Mexican hat'' and furthermore they can be shown to be related to the "Slonczewski resonances.''
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.462812
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