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Photodetachment of WO−3: The electron affinity of WO3 (1991)

Walter, C. W. ; Hertzler, C. F. ; Devynck, P. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 95 (1991), S. 824-827

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Photodetachment cross sections for WO−3 have been measured near the detachment threshold (3.0–3.7 eV). A fast beam of WO−3 is merged with a coaxial cw laser beam and the photodetached electrons are detected with a magnetic confinement slow electron collector. The photodetachment spectrum yields an electron affinity for WO3 of 3.33+0.08−0.15 eV, somewhat lower than values obtained in thermodynamic equilibrium measurements. In addition, a lower limit of 3.7 eV is obtained for the electron affinity of HWO4.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.461089

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