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Equations of state for hard spheres fluid in the metastable fluid region (1991)

Maeso, M. J. ; Solana, J. R. ; Amorós, J. ; [et al.]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 94 (1991), S. 551-555

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: A number of existing approximants are reviewed and tested for the equation of state of the hard spheres fluid in the metastable fluid region, namely, at densities higher than the normal freezing density: ρ*=0.943. This is a region which is particularly sensitive to the quality of a given equation of state; however, it is frequently ignored in the study of analytical equations of state. A new set of approximants is also discussed, including as particular cases several other currently used equations of state for the hard spheres fluid.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.460374

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