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Observation of highly excited bending levels in NCO(X˜ 2Π) (1990)

Patel-Misra, Dipti ; Sauder, Deborah G. ; Dagdigian, Paul J.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 93 (1990), S. 5448-5456

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: New NCO A˜ 2Σ+–X˜ 2Π vibronic bands in the (0,v2,0)–(v1,v2,v3) sequences, with (v1,v3)=(0,0), (1,0), (0,1), (1,1), and (2,0), are reported. These bands have been observed in laser fluorescence excitation experiments of NCO produced in the CN+O2 reaction, where CN was prepared by 193 nm photolysis of cyanogen. The measured bandhead wave numbers were used to derive term values for a number of NCO(X˜ 2Π) vibronic levels, which were then fit to a model Hamiltonian.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.459641

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