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Mapping the van der Waals state space (1989)

Diósi, L. ; Lukács, B. ; Rácz, A.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 3061-3067

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: We show that the metric structures of the thermodynamic state space enables us to uniquely decide if two thermodynamic states belong to the same phase or not, even in the presence of a critical point. While the method cannot classify one state in itself into a definite phase, coherent regions can be identified in the state space. The construction is demonstrated on the van der Waals gas.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.456928

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