Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
89 (1988), S. 6081-6085
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The complete rs structure of the diacetylene cation in the X˜ 2Πg and A˜ 2Πu electronic states is reported. To this end the rotationally resolved origin bands in the A˜ 2Πu –X˜ 2Πg laser excitation spectra of H–13C 3/4 C–C 3/4 C–H+ and H–C 3/4 13C–13C 3/4 C–H+ have been measured and analyzed. From the determined rotational constants as well as those known for H–C 3/4 C–C 3/4 C–H+ and D–C 3/4 C–C 3/4 C–D+, all the bond lengths in the two electronic states have been inferred.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.455423
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