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Mean field theory of nematic order for grafted rods (1987)

Halperin, A. ; Alexander, S. ; Schechter, I.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 86 (1987), S. 6550-6555

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: We consider rod-like polymers which are grafted on a flat surface, such that the grafting sites are mobile. A liquid interface supporting a monolayer of amphiphilic copolymers consisting of rod-like and coil-like parts may realize this model. Using the Onsager approach we find that alignment increases with surface concentration in a continuous fashion. We present diagrams of surface pressure and of nematic order parameter vs surface concentration.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.452397

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