Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
82 (1985), S. 5673-5676
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The rotational relaxation of molecular deuterium in a free jet expansion has been studied between 78 and 473 K by pseudorandom time-of-flight technique. In the temperature range 78–308 K a decrease of the rotational collision number Zrot with increasing temperature is observed as predicted theoretically by Raff and by Rabitz and Lam. Also reported are room temperature data of Zrot for H2 and HD expansions. The number of collisions required to relax H2, D2, and HD at room temperature is in the ratio 10:5:1.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.448554
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