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Dynamic response of an irreversible catalytic reaction to periodic variation of the reactant's pressure (2000)

López, A. C. ; Albano, E. V.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 112 (2000), S. 3890-3896

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The dynamic response of the Ziff, Gulari, and Barshad model for the catalytic oxidation of CO, to a periodic variation of the external pressure is studied close to the CO-poisoning transition. Due to the applied pressure, a considerable enhancement in the catalytic activity is observed when the system is briefly driven into the CO-poisoned state. However, saturation of catalysts' surface can be induced by applying signals of either long period or high amplitude. © 2000 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.480931

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