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Digitale Medien

Molecular constants and Rydberg–Klein–Rees (RKR) potential curve for the Na2 1 3Σg− state (1999)

Liu, Yaoming ; Li, Jian ; Chen, Dieyan ; [weitere]

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 111 (1999), S. 3494-3497

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Details

ISSN: 1089-7690

Quelle: AIP Digital Archive

Thema: Physik , Chemie und Pharmazie

Notizen: Transitions into the doubly excited Na2 1 3Σg− state have been analyzed using near-dissociation expansions (NDE) to represent the vibrational energies and inertial rotational constants, while the centrifugal distortion constants were held fixed at "mechanically consistent" values calculated from the Rydberg–Klein–Rees (RKR) potential implied by those G(v) and Bv functions. The input data cover the range v=0 to 57 and N up to 47, and the fit yields vD=61.41(±0.10) and D0=3385.70(±0.2) cm−1. © 1999 American Institute of Physics.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1063/1.479858

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