Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
109 (1998), S. 10207-10216
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The geometrical structure of Ni39 is probed via molecular adsorption of nitrogen on its surface. Nitrogen uptake patterns are determined at various reaction temperatures, and the results are interpreted in terms of the number and nature of nitrogen binding sites on possible structures. It is found that an adsorbate-induced isomerization occurs at partial nitrogen coverage, but that at saturation a reverse isomerization returns the cluster to its initial structure. The two lowest energy structures calculated by Wetzel and DePristo [T. L. Wetzel and A. E. DePristo, J. Chem. Phys. 105, 572 (1996)] are completely consistent with the observed saturation and isomerization behavior. The structures consist of atom caps packed around a central pentagonal bipyramid, and reflect a marked change from the octahedral structure determined earlier for Ni38.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.477715
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