ISSN:
1551-2916
Source:
Blackwell Publishing Journal Backfiles 1879-2005
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
This paper describes a method for the preparation of silicon nitride (Si3N4) seeds that have an average aspect ratio of ∼4. The seeds are prepared via heat treatment of a powder mixture that contains alpha-phase-rich Si3N4 and 0.5 wt% Y2O3 at a temperature of 1800°C and a nitrogen pressure of 35 kPa. A Y-Si-O-N liquid forms during heat treatment; this liquid acts as a flux for seed precipitation. During cooling, the Y-Si-O-N liquid transforms to a thin intergranular grain-boundary phase and causes strong agglomeration of the seeds. The seeds can be isolated by dissolving the grain-boundary phase in hot phosphoric acid, followed by an ultrasonic treatment (for 30 min). The method can be used to produce large quantities of seeds.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1111/j.1151-2916.1999.tb01969.x
