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Digitale Medien

Optimizing the use of the Kezdy-Mangelsdorf-Swinbourne method for analysis of data following a exp(-kt) + Z (1984)

McKinnon, G. H. ; Backhouse, C. J. ; Kalantar, A. H.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 16 (1984), S. 1427-1454

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The use of the KMS method for the evaluation of the exponent by the experimentalist requires that a lag or retardation be chosen. The best choice of lag is discussed quantitatively. Its dependence upon the decade range of the data, the relative magnitude of the background, the level and character of the noise, the number and distribution of the data, and the weighted least-squares method of analysis are all detailed. A table of lags and error factors is given, for various ranges, backgrounds, and kinds of noise. Bias in the extracted rate (k), due to noise and treatment of the data, is also discussed.

Zusätzliches Material: 10 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550161112

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