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Digitale Medien

Dynamic mechanical studies of endgroup-modified polystyrene (1974)

Fellers, J. F. ; Rahbar-Semanani, M.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 12 (1974), S. 2035-2043

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Details

ISSN: 0360-6376

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Polystyrenes having both modified and unmodified endgroup structures were synthesized. These polystyrenes were then subjected to dynamic mechanical testing below their glass transition temperature. The modified structures were shown to influence the β transition of polystyrene. While the mechanism of this secondary transition has been speculated but never unequivocally substantiated in the past, the evidence presented here strongly support the idea that the β transition of polystyrene arises from chain-end motions.

Zusätzliches Material: 5 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1974.170120917

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