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Raman studies of reorientational relaxation of cyclohexane in the liquid state (1982)

Bien, T. ; Döge, G.

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 12 (1982), S. 82-85

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Reorientational correlation functions have been obtained from the analysis of the totally symmetric vibrations ν4, ν5 and ν2 of liquid cyclohexane. For the interpretation of the data, the Kubo line shape theory was assumed to be valid. The most reliable results were obtained from the ν4 vibration and indicated that reorientational relaxation occurs close to the Debye limit of rotational diffusion. The data are compared with NMR results given in the literature. The effects of rotational-vibrational coupling are discussed.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250120113

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