ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Electrochemical Syntheses, XX1). The Syntheses of S4N4 and (S5N5)ClThe cathodic reduction of S3N3Cl3 in 0.1 M (Ph3P=N=PPh3)[PF6]/CH2Cl2 or 0.15 M (Bu4N)-[BF4]/CH2Cl2 yields S4N4 at room temperature and (S5N5)Cl at - 20°C with current efficiencies of 90% and 49%, respectively.
Notes:
Die kathodische Reduktion von S3N3Cl3 in 0.1 M (Ph3P=N=PPh3)[PF6]/CH2Cl2 oder 0.15 M (Bu4N)[BF4]/CH2Cl2 ergibt bei Raumtemperatur S4N4 und bei - 20°C (S5N5)Cl mit Stromausbeuten von 90% bzw. 49%.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19841170520