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The reactions of S(3PJ) atoms with thiiranes (1984)

Van Roodselaar, A. ; Safarik, I. ; Strausz, O. P.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 16 (1984), S. 899-907

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The reactions of ground-state S(3PJ) atoms with thiirane, methylthiirane, and trans-2,3-dimethylthiirane have been studied by flash photolysis-VUV kinetic absorption spectroscopy. From the analysis of the S(3PJ) decay plots the following rate constants were determined: (1.4 ± 0.2) × 1013, (2.7 ± 0.3) × 1013 and (4.0 ± 0.2) × 1013 (in cm3 mol-1 s-1 units) for thiirane, methylthiirane and trans-2,3-dimethylthiirane, respectively, showing an upward trend with increasing methylation.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550160710

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