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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 1111-1115 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Rate constants for the self- and cross-termination of the isopropylol radical [(CH3)2ĊOH] and its anion [(CH3)2ĊO-] in aqueous solution are determined by kinetic electron spin resonance. Whereas the self-termination of the neutral radical occurs close to the diffusion-controlled limit, the cross- and self-terminations involving the anion are slower and reflect effects of charge repulsion and steric constraints by solvation.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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