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The pyrolysis of octafluorocyclobutane - Revisited (1998)

Bauer, S. H. ; Javanovic, S.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 30 (1998), S. 171-177

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A high-pressure, high-temperature reactor unit was developed to test batch-wise inter-conversions of hydrocarbons. A major ambiguity characterizes this reactor, as it does all similar units that have been described, determination of the time-temperature profile for the reacting mixture. Here we report on a solution to this problem - use of a “chemical thermometer,” based on the kinetics of dissociation of C4F8. We propose a revised set of rate constants that permit calibration of the reactor operation. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet 30: 171-177, 1998.

Additional Material: 10 Ill.

Type of Medium: Electronic Resource

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