ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A discharge flow reactor coupled to a laser-induced fluorescence (LIF) detector and a mass spectrometer was used to study the kinetics of the reactions CH3O+Br→products (1) and CH3O+BrO→products (2). From the kinetic analysis of CH3O by LIF in the presence of an excess of Br or BrO, the following rate constants were obtained at 298 K: k1=(7.0±0.4)×10-11 cm3 molecule-1 s-1 and k2=(3.8±0.4)×10-11 cm3 molecule-1 s-1. The data obtained are useful for the interpretation of other laboratory studies of the reactions of CH3O2 with Br and BrO. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet 30: 249-255, 1998.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource