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Kinetic evidence for the reaction of O•- radical ions and peroxodisulfate in alkaline aqueous solutions (1998)

Mártire, Daniel O. ; Gonzalez, Mónica C.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 30 (1998), S. 491-496

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Photolysis of S2O8= in strong alkaline solutions (pH 〉 13) in the presence of molecular oxygen yields ozonide radical ions, \documentclass{article}\pagestyle{empty}\begin{document}$ \rm{O^{\textstyle{\cdot}-}_{3}} $\end{document}. These radicals show a complex decay rate sensitive to the peroxodisulfate concentration. A reaction mechanism, which includes the reaction of O•- and S2O8= with a rate constant k=(3-6)×106M-1s-1 and accounts for the experimental results is discussed. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet: 30: 491-496, 1998

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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