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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 30 (1998), S. 589-594 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Using a relative rate method, rate constants for the gas-phase reactions of 2-methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at 298±2 K and 740±5 torr total pressure are: kOH=(3.9±1.2)×10-11 cm3 molecule-1 s-1, kO3=(8.6±2.9)×10-18 cm3 molecule-1 s-1, kNO3=(8.6±2.9)×10-15 cm3 molecule-1 s-1, and kCl=(4.7±1.0)×10-10 cm3 molecule-1 s-1. Atmospheric lifetimes have been estimated with respect to the reactions with OH, O3, NO3, and Cl. The atmospheric relevance of this compound as a precursor for acetone is, also, briefly discussed. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet: 30: 589-594, 1998
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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