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Photoreduction of IrCl62- complex in alcohol solutions and its reaction with hydroxyalkyl radicals (1998)

Glebov, E. M. ; Plyusnin, V. F. ; Grivin, V. P. ; [et al.]

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 30 (1998), S. 711-719

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The photochemistry of IrCl62- complex in simple alcohols have been studied using laser-flash photolysis. Single electron transfer from the solvent molecule to the light-excited complex has been shown to be the primary photochemical process. Quantum yields of the photoreduction of IrCl62- complex and the rate constants of its reaction with hydroxyalkyl radicals were determined at 200-330 K. Deviations of the rate constants from Debye-Smoluchowski equation for diffusion-controlled reactions are discussed. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet: 30: 711-719, 1998

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

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