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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 299 (1959), S. 138-150 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The bonds between silicium and elements of a great electronegativity are customary stronger than single bonds. This is shown by the valence force constants. The valence frequencies of substituted compounds indicate that strong electronegative substituends strengthen adjacent bonds. The mechanism of this strengthening is discussed.
    Notes: Die Valenzkraftkonstanten für Bindungen zwischen Silicium und stark elektronegativen Partnern zeigen, daß diese Bindungen in der Regel stärker als normale Einfachbindungen sind. Die Valenzfrequenzen in gemischt substituierten Verbindungen lassen erkennen, daß stark elektronegative Substituenten benachbarte Bindungen verstärken. Der Mechanismus dieser Bindungsverstärkungen wird diskutiert.
    Additional Material: 18 Tab.
    Type of Medium: Electronic Resource
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