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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 2 (1989), S. 187-204 
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Reaction products of bifunctional chain molecules with structure X—(CH2)n—Y may critically depend on the chain length n. When the chain length is short (n ≤ 5), reaction products particular to an intramolecular reaction can be dominant, while a process corresponding to an intermolecular reaction between X—CH3 and H3C—Y may take place for higher homologues having large n (≥10). The reaction switching dependent on n is explained in terms of the encounter probability for both end groups (X and Y) with conformations pertinent to product formation. The reaction switching of this sort is discussed on the basis of a reactivity profile recorded as a function of the chain length. Similar reactivity profiles have been observed for thermal Friedel-Crafts cyclization and photo-Smiles rearrangement/photoredox reaction. It is anticipated that the magic methylene chain length of 7 may give rise to an appreciable decrease in reaction yields (e.g. ‘difficulty in medium-sized ring closure’) or an anomalous switching of reaction pathways due to chain length effects.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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