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  • 1
    Electronic Resource
    Electronic Resource
    Molecular weight phenomena at high conversions in the Ziegler-Natta polymerization of butadiene (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 1461-1470 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A Comparison between two different feedstocks in the homogeneous polymerization of butadiene has been conducted. The conversion and molecular weight trends were essentially the same for both feedstock systems. Changes in polydispersity at high conversions could not be explained by a living polymerization mechanism. A reaction scheme involving reuse of active cobalt centres combined with termination has been proposed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170220624
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