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PVC miniemulsion polymerization. I. Origin of droplet families (1984)

Dewald, R. C. ; Hart, L. H. ; Carroll, W. F.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2923-2930

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Details

ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A soap/alcohol miniemulsion in combination with an homogenized mixture of monomer and initiator is utilized to generate PVC plastisol. Droplet distributions generated consist of two distinct types. Judicious control of soap-to-alcohol ratio allows control of the number and size of the smaller droplet family; homogenization and initiator water solubility affect the other. Final latex particle distribution may be unimodal or bimodal depending upon manipulation of these factors.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1984.170221115

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