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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 1 (1963), S. 1709-1720 
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Various self-diffusion and nuclear relaxation experiments are reported for a polyisobutylene of rather low molecular weight, in bulk and in solution. In the bulk, the self-diffusion coefficient obeys the Arrhenius relation, yielding an activation energy of 5.5 kcal./mole. In solution the activation energies are lower, approaching the value for the solvent at low concentration. The self-diffusion coefficient of the polymer at infinite dilution is 1.2 × 10-5 cm.2/sec. in CS2 and 0.44 × 10-5 cm.2/sec. in CCl4. The ratio is close to the inverse ratio of the solvent viscosities. Measurements of self-diffusion of the solvent have been made for cyclohexane in polyisobutylene. A simple interpretation of the data in terms of Stokes-Einstein models yields molecular dimensions which are too small by a factor of two or three.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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