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Nuclear magnetic relaxation in polymer melts and solutions (1962)

McCall, David W. ; Douglass, Dean C. ; Anderson, Ernest W.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 59 (1962), S. 301-316

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Nuclear magnetic relaxation times have been studied in some polymer liquids and solutions. The nonexponential decay of the transverse magnetization has been ascribed to the distribution of molecular weights. The use of such measurements as a means of determining average molecular weights and distributions is discussed. A preliminary application of this use is made for polyethylene. The implications of nuclear magnetic relaxation measurements are discussed in terms of molecular motional processes of the polymer chains.

Additional Material: 8 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1962.1205916808

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