ISSN:
1432-0630
Keywords:
33.40
;
34.50
;
35.20
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract A novel spectroscopic method for highly sensitive detection of hot-band transitions based on infrared-infrared double resonance in a molecular beam was successfully demonstrated. The intensity of the infrared transitions from a vibrationally excited state is enhanced by two orders of magnitude by resonant laser pumping. The hot-band transitions are identified in connection with the assigned transitions in the fundamental band. Doppler-free spectral lines are observed. The experiment was carried out on the 2v 3←v 3 transitions of CH3F with CO2 laser pumping and probing.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00899760