ISSN:
1612-1112
Keywords:
Gas chromatography
;
Gas solubilities
;
Enthalpies of solution
;
Polar solutions
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The gas-liquid chromatographic method has been used to determine the solubilities and partial molar enthalpies of solution of the gases H2S, CO2 and COS in four polar solvents. The results agree well with literature values obtained using conventional techniques, with the one exception of H2S in N-methyl-2-pyrrolidinone. In this case there is some evidence for the occurrence of adsorption at the gas-liquid interface.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02265810