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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 3100-3110 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Antimony clusters are produced by the gas aggregation method. They are found to be built from Sb4 units. The Sb+4n clusters are demonstrated to relax their excess energy by evaporation of a tetramer and the binding energy of Sb4 in the cluster is measured to be about 1.3 eV, well below the binding energy of a Sb atom in the bulk (≈2.75 eV). The ionization potentials of Sb4n clusters are studied as a function of the size and the observed evolution confirms the nonmetallic character of their structure. These results are compared with those obtained for bismuth clusters which exhibit a very different behavior. Finally the possible metastable character of Sb4n structure is discussed and illustrated by experiments performed as a function of inert gas temperature in the clusters source.
    Type of Medium: Electronic Resource
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