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Complete kinematic measurement of three-body reaction dynamics: Dissociative photodetachment of O6− at 532 nm (1998)

Hanold, K. A. ; Luong, A. K. ; Continetti, R. E.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 109 (1998), S. 9215-9218

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Measurement of the translational energy partitioning in the three-body dissociative photodetachment of O6− (O6−+hν→O2+O2+O2+e−) at 532 nm is reported. Using photoelectron and photofragment translational energy spectroscopies in coincidence, a complete kinematic measurement of the three-body dissociation of neutral O6 is obtained. Vibrationally resolved product translational energy distributions are observed. The results provide insights into the structure, binding energy, and dissociation dynamics of O6− and O6 and illustrate a new approach to the study of three-body reaction dynamics. © 1998 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.477580

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