Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
102 (1995), S. 6385-6399
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
High resolution synchrotron photoelectron spectra (PES) of ethylene have been obtained at several photon energies in the range 30 to 220 eV. Further evidence is presented that the correlation (satellite) peak at 27.4 eV binding energy is "intrinsic'' in nature. A new correlation peak at 21.4 eV binding energy, however, is found to be a "dynamic'' correlation. Several PES of 1-13C-ethylene have also been obtained and have been found to be identical to those of normal ethylene. Both of the correlation peaks are also present in the labeled species with similar photon energy behaviors. Sophisticated theoretical calculations are found to agree quantitatively with the experimental PES spectra. © 1995 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.469354
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