ISSN:
1435-1536
Keywords:
Zeolite
;
modification
;
chloroform
;
adsorption
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract Adsorption characteristics of chloroform from its aqueous solution on Na−Y and Li−Na−Y modified by SiCl4 were measured and compared with those on Na−ZSM-5 and Na-Mordenite. No adsorption occurred on Na−Y with high hydrophilicity, while the siliceous faujasites became capable of adsorption and its amount increased with increase in the Si/A1 ratio. Adsorption isotherms are of Langmuir type, suggesting that adsorption proceeds by pore filling. The adsorption amounts expressed in volume on Na−Y with high hydrophobicity corresponded to their pore volumes. Adsorption characteristics of chloroform from gaseous phase on Na−Y with different Si/A1 ratio were also measured. The adsorption capability decreased with increasing Si/A1 ratio. Immersional heats of zeolites into water or chloroform were measured in order to evaluate the surface affinity to both solvents. Immersional heats into water were almost constant (about 500 mJ·m−2) for zeolites with their Si/A1 ratio below 10. The heats decreased with an increase in the Si/A1 ratio above 10, then became almost constant (about 120 mJ·m−2) over 30 in their ratio. Heats of immersion of Na−Y series into chloroform were almost constant irrespective of their Si/A1 ratio, but decreased slightly when the ratio exceeded 20. Adsorption characteristics of chloroform could be well related to immersional heats into both solvents.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00664730
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