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Digitale Medien

Studies of the electronic Raman spectra of atomic chlorine excited by an argon ion laser (1984)

Chang, Hua ; Lin, Hong Ming ; Hwang, Mei Hua

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 15 (1984), S. 205-210

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Details

ISSN: 0377-0486

Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: The electronic Raman transition hetween 2P3/2 and 2P1/2, states has been found at 882.5 cm-1 for atomic chlorine. The intensity of this peak increased quadratically with increasing laser power. Therefore, the process involved one, and only one, photon in producing Cl. A model of photodissociation and photopredissociation is suggested, which could explain the dependence of the relative intensity on the laser frequency as well as the laser power. This model also predicts the population ratio of Cl in the two atomic states; the experimental results agreed with the predicted values.

Zusätzliches Material: 5 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/jrs.1250150314

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