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  • 1990-1994  (7)
  • 1960-1964
  • 1990  (7)
  • 1
    Electronic Resource
    Electronic Resource
    High intensity electron channeling and perspectives for a bright tunable x-ray source (1990)
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 57 (1990), S. 2956-2958 
    Details
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Using the continuous wave electron beam of the new Darmstadt superconducting electron accelerator and high intensity axial channeling in a diamond crystal, the possibility for the production of an intense tunable photon source in the x-ray region is investigated. Due to low emittance of the machine and its high current it has become possible, for the first time, to produce channeling radiation in the energy region of a few keV with an intensity of up to 2×1010 photons/s in an x-ray energy window of 10%. This is six orders of magnitude more than what has been observed previously.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.103738
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Susceptibility ofHeliothis zea (Boddie) larvae toNomuraea rileyi (Farlow) Samson (1990)
    Springer
    Journal of chemical ecology 16 (1990), S. 1751-1759 
    Details
    ISSN: 1573-1561
    Keywords: Heliothis zea ; Lepidoptera ; Noctuidae ; Nomuraea rileyi ; Deuteromycotina ; fungi ; α-tomatine ; allelochemical ; third trophic level
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract To determine the impact of α-tomatine at the third trophic level, the following model was developed:Nomuraea rileyi (Farlow) Samson, the secondary consumer, acting onHeliothis zea (Boddie), the primary consumer, fed an artificial diet modified with α-tomatine. In vitro, the allelochemical inhibited colony formation and growth of the fungus. The in vivo test revealed that larval growth and developmental time were affected by α-tomatine andN. rileyi. Detrimental effects on pupal development were observed in larvae fed diet containing α-tomatine and also treated withN. rileyi (LC90). The fungus was detected in the hemolymph and tissue of larvae treated with two lethal concentrations (LC50 and LC90) ofN. rileyi, including those fed α-tomatine. At the LC50, α-tomatine protected larvae againstN. rileyi and increased survivorship; at the LC90, it inhibited the development ofN. rileyi, thereby reducing production of conidia. Thus, the allelochemical α-tomatine retains its antifungal qualities beyond the second trophic level, inhibiting the development ofN. rileyi inH. zea.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01020492
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Electroexcitation of magnetic dipole and other modes in46Ti and48Ti (1990)
    Springer
    The European physical journal 336 (1990), S. 159-178 
    Details
    ISSN: 1434-601X
    Keywords: 21.60.-n ; 25.30.Dh ; 27.40.+z
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract With high-resolution inelastic electron scattering measurements on46Ti and48Ti the excitation mechanism of the transition into low lying Jπ=1+ states is investigated. The experimental evidence of considerable contribution of the orbital part of theM1 operator to the total transition strength is given by a model dependent analysis of form factors. The possibility of physical relationship to low lying Jπ=1+ states in the rare earth nuclei is discussed in various models. MoreoverE2 form factors and good candidates forM3 form factors are presented.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01290617
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  • 4
    Electronic Resource
    Electronic Resource
    Nonlinear phenomenon of interfacial polarization immittance of a Pt electrode (1990)
    Springer
    Annals of biomedical engineering 18 (1990), S. 505-518 
    Details
    ISSN: 1573-9686
    Keywords: Electrode ; Nonlinear system ; Measurement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: Abstract Description of a computerized, automated method to measure the interfacial polarization immittance of a Pt electrode in nonlinear range is presented. The classical three-electrode setup is used for measurements in conjunction with a special purpose software implemented on a Unix computer using C language. A collection of data at very low frequencies (below 2 Hz) and at high input intensities with various dc biases imposed on the input are presented to show the behavior of the interface in nonlinear range. The instrument also provides on-line harmonic analysis of the output signal, by calculating the first four Fourier series coefficients, in response to a pure sinusoidal input.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02364614
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  • 5
    Electronic Resource
    Electronic Resource
    Heterocyclisch substituierte Arendiazoniumsalze mit erweiterter spektraler Empfindlichkeit. II. 4-(1-Heterocycliden-2,3-diaza-prop-2-en-3-yl)-benzendia-zoniumtetrafluoroborateHerrn Prof. Schulz zum 60. Geburtstag gewidmet (1990)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 332 (1990), S. 43-54 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Heterocyclic Substituted Arenediazonium Salts with a Long-wave-length Range of Sensitivity. II. 4-(1-Heterocycliden-2,3-diaza-prop-2-en-3-yl)-arenediazonium tetrafluoroboratesThe title compounds (3) are obtained by reaction of aromatic bis-diazonium salts with substituted 2-benzylidene-1,3-dithioles and 2-benzylidene-1,3-diselenole, respectively. The maximum of the long wave-length absorption band of 3 varies from 580 nm up to 665 nm depending on the structure of the compound.The quantum yields of the photolysis of the diazonium salts 3 are low (1 · 10-4 to 7 · 10-3). The azo dyes obtained from 3 with usual azo-couplers absorb in a shorter wave-length range than the corresponding diazonium salts themselves (hypso-coupling effect).
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19903320106
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  • 6
    Electronic Resource
    Electronic Resource
    Lewis-Säure- und photochemisch induzierte Dimroth-Umlagerung von 3H,6H-2,5-Bis-(p-N,N-dimethylaminophenyl)-1,2-thiazolino[5,4-d]1,2-thiazolin-3,6-dithion (1990)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 332 (1990), S. 387-393 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Lewis-acid and Photochemically Induced Dimroth Rearrangement of 3H,6H-2,5-Bis-(p-N,N-dimethylaminophenyl) -1,2-thiazolino[5,4-d]1,2-thiazoline-3,6-dithioneThe reaction of 3H,6H-1,2-dithiolo[4,3-c]1,2-dithiole-3,6-dithione (5) with N,N-dimethyl-p-phenylendiamin gives, depending on the conditions of the reaction, 3H,6H-3-(p-N,N-dimethylaminophenyl-imino)-1,2-dithiolo[4,3-c]1,2-dithiole-6-thione (7), and 3H,6H-2,5-Bis-(p-N,N-dimethylaminophenyl) -1,2-thiazolino[5,4-d]1,2-thiazoline-3,6-dithione (3d). Catalyzed by Lewis acids the compound 3d rearranges reversibly into the isomeric 3H,6H-3,6-bis-(p-N,N-dimethylaminophenyl-imino) -1,2-dithiolo[4,3-c]1,2-dithiole (4d). The Dimroth type rearrangement of 3d into 4d occurs also on irradiation.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19903320317
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  • 7
    Electronic Resource
    Electronic Resource
    NMR-Untersuchungen zu Struktur und Beweglichkeit von substituierten Polyacetylenen (1990)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 41 (1990), S. 522-527 
    Details
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly(bis-methylthio-acetylene) and poly(bis-ethylthio-acetylene) were investigated by 13C-NMR with respect to the structure of the main chain and the mobility of the side chains. The main chain consists of sp2-hybridized carbon atoms. The 1,2-bisalkylthylen units build up a nonplanar polymer backbone, which does not show any discrete configurations. In poly(bis-methylthio-acetylene) the MeS units undergo a rotational diffusion motion with a resorentation rate of about 70 kHz. The electron spin dynamics have on importance within the main chain.
    Notes: Poly(bis-methylthio-acetylen) und Poly(bis-ethylthio-acetylen) wurden hinsichtlich der Struktur der Hauptkette und der Beweglichkeit der Seitenketten mittels 13C-NMR-Spektroskopie untersucht. Die Hauptkette bestecht aus sp2- hydridisierten C-Atomen. Die 1,2-Bisalkythioethylen-Einheiten bilden ein nicht-Planares Polymerrückgrat, für das keine distreten Konfigurationen nachzuweisen sind. In Poly(bis-methylthio-acetylen) führen die MeS-Einheiten eine Rotationsdiffusionsbewegung von etwa 70 kHz aus. Innerhalb der Hauptkette hat die Elektronenspindynamik keine Bedeutung.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/actp.1990.010411003
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